James & Son
Veteran Member
I have a theory that has slowly been developing. I wonder if Toolslick has these theories as well since it is oil and follower related. Maybe eddif might wake up.
The more calcium dispersant you have in the oil the more Zddp can be added without running into to much issues. This is because calcium prevents to some degree the hard glass forming and allows a softer film to form at a lower temperature and pressure.
http://www.apmaths.uwo.ca/~mmuser/Papers/TL05.pdf
I do not like to much boron and less than 20% maganesium ralative to the amount of calcium dispersant for this reason.
I am guessing here but I think some of the problems with the black follower and break in issues can be solved by playing with the amount of zddp and calcium ratio in a break in oil.
Soft break in of black follower use 2700/3000 parts calcium with 1600 to 2100 parts Zddp and a 10w-40 synthetic or a 15w-40 group II oil.
Edit- After reading all the posts on the low operating and warm up temps. I think I should change my thermostat and look for a stock or 90 C stat. I have noticed the oil cooler warms the oil before the filter to room temp. in less than 3 minutes even in winter.
I will be pulling my cam shaft shortly to verify this very break-in theory.
Edit
Simply put, an effective AW film will cross-link at pressures below the pressure (bulk modulus) of the target substrate and remain softer than the substrate.
Effect of calcium…..a positive aspect of this behavior is that softening the film through the incorporation of cations, such as calcium, may reduce abrasion of softer sub-strates.
I want to add to the above quotes I pulled from the study.
[a] boron adds to the hardness of the glass forming of Zddp.
By minimizing the slippage on the lobe apex as it rolls over the follower center point one should have minimal wear on both the lobe apex and the center portion of the black follower. Therefore an oil with high shear ( strong molecular attraction to steel) and minimal anti friction compounds and zddp only as AW will have high traction if I can use the term in reference to the rotation of the black follower.
Update Edit:
http://www.bobistheoilguy.com/forums/ubbthreads.php?ubb=showflat&Number=258013
Some interesting reading on calcium magnesium and sulphated ash.
The more calcium dispersant you have in the oil the more Zddp can be added without running into to much issues. This is because calcium prevents to some degree the hard glass forming and allows a softer film to form at a lower temperature and pressure.
http://www.apmaths.uwo.ca/~mmuser/Papers/TL05.pdf
I do not like to much boron and less than 20% maganesium ralative to the amount of calcium dispersant for this reason.
I am guessing here but I think some of the problems with the black follower and break in issues can be solved by playing with the amount of zddp and calcium ratio in a break in oil.
Soft break in of black follower use 2700/3000 parts calcium with 1600 to 2100 parts Zddp and a 10w-40 synthetic or a 15w-40 group II oil.
Edit- After reading all the posts on the low operating and warm up temps. I think I should change my thermostat and look for a stock or 90 C stat. I have noticed the oil cooler warms the oil before the filter to room temp. in less than 3 minutes even in winter.
I will be pulling my cam shaft shortly to verify this very break-in theory.
Edit
Simply put, an effective AW film will cross-link at pressures below the pressure (bulk modulus) of the target substrate and remain softer than the substrate.
Effect of calcium…..a positive aspect of this behavior is that softening the film through the incorporation of cations, such as calcium, may reduce abrasion of softer sub-strates.
I want to add to the above quotes I pulled from the study.
[a] boron adds to the hardness of the glass forming of Zddp.
By minimizing the slippage on the lobe apex as it rolls over the follower center point one should have minimal wear on both the lobe apex and the center portion of the black follower. Therefore an oil with high shear ( strong molecular attraction to steel) and minimal anti friction compounds and zddp only as AW will have high traction if I can use the term in reference to the rotation of the black follower.
Update Edit:
http://www.bobistheoilguy.com/forums/ubbthreads.php?ubb=showflat&Number=258013
Some interesting reading on calcium magnesium and sulphated ash.
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