First off, I would recreate the climb, but use VCDS to scan the actual coolant temp. The gauge is dumbed down and may be peaking to 200 even though it's only at 195...
Other than the other common cooling system items, (T-stat, rad etc) I would proactively change the coolant temp sensor to ensure that it's at lease reading correct. Have seen more than one car "overheat" when it was only the temp sensor reading 10 degrees high...