Why not use the head gasket to achieve the same clearance tolerances?
The proper way to off-set milling the head is to remove material off the the Valve Face and Valve Seat as csstevej stated. It has been a long time since I looked in the Bentley Manual, but if I remember correctly, there is a small tolerance that doesn't require modifying either the valve or seat.
Example: Several years ago, a friend of mine had a local shop to "cut" the head on his TDI engine. The cutter left rather large streaks in an arc from one end of the head to the other. The valves and seats were not modified. The head was installed but leaked almost immediately. There was no valve to piston contact. The head was removed and sent to a shop that used a "wet" milling process to clean-up the mess. Then the guy had the local shop to modify the valves and seats. I loaned him my Bentley Manual to follow the specifications. He also took material off the end of the valve stems which is not recommended, if I remember correctly.
I do not know how much, in total, was milled off the head. I do not know how much was cut off the valves and seats nor how much was removed from the valve stems.
I do know the head gasket thickness was not changed.
I do know the engine ran just fine and the vehicle is still on the road.
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Note: Seems I told this story recently in a different Thread. If I told it here, I apologize for being repetitive.)
You've been given good solid advice by experienced veteran members. I'm not sure what else they can offer.
The best way to improve performance is not thru increasing the compression by changing the head gasket thickness. An appropriate tune, bigger turbo (with appropriate tune), larger nozzles, 11mm IP head vs the 10mm, any combo of all, etc., is the best way to improve performance.