rotary, I was using propane as a synonym for an HC blend because the common HC blends are mixtures of propane and butane.
I tried a propane/butane blend. No leaks before I evacuated the system. I refilled and could smell the lemony scent used as a leak detector afterwords. I ended up changing hoses that were fine because I could smell the scent through the rubber hoses at the front of the car (and it would lose its refrigerant charge after a month). Even with new hoses it was still leaking!
I refilled with HFC R134a and it stopped leaking and never had a problem for years.
In short: the HC blend was leaking through the rubber hose, not the o-rings.
I've seen what you describe several times in HFC-134a spec'ed systems . And due to the lack of knowledge available in the US I'm not surprised of your experience . The hoses you replaced I'm sure there was nothing wrong with them , here is what I'm sure you experienced ;
What I bet was happening was the overpressure valve was opening and expelling part of the charge when the sun's heat made the charge expand in the system . The expansion rate of HC blends is many times that of HFC-134a , 6 ozs of an HC blend ~ 16 ozs of HFC-134a . As I stated you only need a small % of the charge HFC required to cool .
What I have seen happen is in order to get a HC blend to bleed down in the evaporator within the HFC spec range of 38-40 to 55 psig the system must be overfilled . What happens is the system will stay charged until in the heat of the sun the HC blend expands overfilling the system . The overcharge which is required to reach HFC bleed down specs expands in the heat to the point that it bleeds out of the overpressure valve . When the temps are normalized again the charge is too low to reach the higher HFC spec bleed down pressures so no cooling .
If the system bleed down spec was lowered by modifying the bleed down opening pressures to 25 to 38 psig the remaining charge would cool many times better than the origional HFC-134a charge . I've made this change to many HFC-134a systems . On a modified stock HFC system as much as 20*F drop in cooling temp can be documented .
If the system is filled to capacity with a 100 % HC blend the bleed down pressure will be 25-38 psig . In order to switch an HFC spec system to a 100 % HC blend charge the bleed down spec pressure must be modified to operate in the lower pressure range .
What many people do is add a can of HFC-134a to a HC blend charge which changes the bleed down characteristics to more match HFC-134a spec . I've seen this bring the evaporator pressure bleed down spec to match the design spec of a HFC system . And the plus is the mix of refrigerants retains the much higher efficiency , as much as a 20 *F drop in cooling temp of the HC blend . On modified and mixed systems I've seen cooling air temps drop from struggling to reach 40-45*F in ~90-95*F ambient suddenly able to reach mid 10s*F ( 15-18*F ) in the same ambient .
A note for anyone that cares it's illegal for an individual to mix refrigerants which is stupid . A stupid law that really makes no sense today because all refrigerants are blends of some sort , even many of the HFC-134a refill charges are blends of some sort ( Usually an HC blend of some sort ) . What mixing does is raise the bleed down pressure to within spec of how the system is set up without requiring the system volume of the charge being overfilled .
The other thing people do is disable the bleed down overpressure valve , I don't recommend that one . A HC blend filled system operates @ much lower pressures so a disabled overpressure valve would likely not cause any problems . But if it were ever to fill the system with HFC-134a again the valve would have to be enabled again to prevent explosive lose of pressure . HC blend charge pressures max out short of 350-400 psig on the high side while 550 to 600+ psig can easily be reached on the high side with an HFC charge with a condenser fan failure .
In the US there seems to be a "head in the sand" attitude when it comes to refrigeration . I've learned what I know about HC blends from working on freezers , home ac , auto and farm equipment ac CFC spec systems .
I was taught about CFCs and HFCs in college , much of what they told us in school I've learned was not based on reality but was political bullsh!t . I learned first hand what different mixes of refrigerants can do and what they can't . Many of the things I've learned first hand were expressly forbidden from what I learned in college , again political bullsh!t . Today HC blends are the norm of/in all refrigerants on the market today since CFCs are being completely banned .
HC blends are environmentally friendly and the only refrigerants that can preform close to what chlorine based refrigerants could do . HFC-134a is being replaced with a HC blended refrigerant the end of next year if today's mandates are carried through on .