You'll need to use Adv Meas Values since your engine controller is UDS as explained here:
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Those are both "ghost" controllers, that don't really exist but that the factory VW protocols (and scan tools) can ping for some reason. 33 is Generic OBD-2 so if you were using an old VAG-1552 you could check it by pressing 33 then Q. In VCDS the equivalent is to click on OBD-2 from the main...
What does your interface say on it, all of the writing? Even if you aren't the original purchaser we can help look into reasons why it might not work. Feel free to email instead of posting if you want.