Cetane boost from additives.

b4black

Veteran Member
Joined
Dec 18, 2004
Location
IL
TDI
1998 Jetta blue
I found this graph in a presentation online. It is the amount of cetane increase from using 2-ethylhexyl nitrate (2-EHN), the most common cetane improving additive. Afton (HiTEC brand) is the biggest supplier of this additive in raw form. Aftermarket companies typically buy this additive and mix it into their own "cocktail". Most often at about 30% of the total. (Straight 2-EHN is dangerous to handle and not available on the shelf).

Compare this graph to your additive's treatrate and see what you get.

http://www.dieseltruckresource.com/dev/attachment.php?attachmentid=26928&d=1237383541
 

tditom

Top Post Dawg
Joined
Sep 5, 2001
Location
Jackson, MI
TDI
formerly: 2001 Golf GL, '97 Passat (RIP) '98 NB, '05 B5 sedan
the x-axis shows the % volume of HiTEC.

the results differ based on the original cetane index of the fuel- interesting.
 

mrGutWrench

Top Post Dawg
Joined
Aug 29, 2002
Location
Carrboro, NC
TDI
'03 Jetta Wagon, 5-speed, 563K Miles (July '23)
b4black said:
I found this graph in a presentation online. It is the amount of cetane increase from using 2-ethylhexyl nitrate (2-EHN), the most common cetane improving additive. (snip)
__. The graph follows the usual rule that's been stated here -- double the amount of additive gives you half the improvement in cetane.
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
Chevron said:
Engine and Fuel Delivery System Performance Additives

This class of additives can improve engine or injection system performance. The effects of different members of the class are seen in different time frames. Any benefit provided by a cetane number improver is immediate, whereas that provided by detergent additives or
lubricity additives is typically seen over the long term, often measured in thousands or tens of thousands of miles.

Cetane Number Improvers (Diesel Ignition Improvers)

Cetane number improvers raise the cetane number of the fuel. Within a certain range, a higher number can reduce combustion noise and smoke and enhance ease of starting the engine in cold climates. The magnitude of the benefit varies among engine designs and operating modes, ranging from no effect to readily perceptible improvement.

2-Ethylhexyl nitrate (EHN) is the most widely used cetane number improver. It is also called octyl nitrate. EHN is thermally unstable and decomposes rapidly at the high temperatures in the combustion chamber. The products of decomposition help initiate fuel combustion and thus shorten the ignition delay period from that of the fuel without the additive.


The increase in cetane number from a given concentration of EHN varies from one fuel to another. It is greater for a fuel whose natural cetane number is already relatively high. The incremental increase gets smaller as more EHN is added, so there is little benefit to exceeding a certain concentration. EHN typically is used in the concentration range from 0.05 to 0.4 percent mass and may yield a three to eight cetane number benefit. A disadvantage of EHN is that it decreases the thermal stability of some diesel fuels. This can be compensated for by the use of thermal stability additives.

Chevron said:
Contrary to intuition, two fuels that, by themselves, have good stability may form a less stable blend when they are combined. In this case, each fuel contains some of the precursors needed for the formation of higher molecular weight species. Only when the fuels are mixed are all the precursors available, enabling the conversion to proceed.

Another example of an unexpected interaction involves 2-ethylhexyl nitrate (EHN) (diesel ignition improver or cetane number improver). The addition of EHN to a fuel or the blending of fuels, one of which contains EHN, may increase thermal instability because the decomposition of EHN promotes the reactions that lead to higher molecular weight species.

As of the date of this publication, there is not enough experience with S15 diesel fuel stability. (S15 is the ASTM international designation for diesel fuel with 15 ppm or less sulfur.) Since many of the species that can form particulates are removed during hydrotreatment, it is believed that S15 diesel will have excellent thermal stability and not react with the cetane number improver ethylhexyl nitrate. However, there is some concern that S15 diesel, without the natural oxidation inhibitors which are removed by hydrotreating, may form peroxides during long-term storage.














Diesel Fuels, Technical Review 2007









 

BKmetz

Administrator, Member #10
Staff member
Joined
Sep 25, 1997
Location
Illinois
TDI
2015 Passat, titanium beige, 6MT
Typically there is a plateau effect where there is no more performance gained even though more additive is used. The graph supports that.
 

Drivbiwire

Zehntes Jahr der Veteran
Joined
Oct 13, 1998
Location
Boise, Idaho
TDI
2013 Passat TDI, Newmar Ventana 8.3L ISC 3945, 2016 E250 BT, 2000 Jetta TDI
Turbo Steve said:
Sometimes a high-quality fuel (like the TDI Founding Fathers envisioned) of the proper cetane value is "not available" is your area and a cetane boost additive is necessary to help get the numerical value up to what VW recommends. In this case, I suggest that you consider AMSOIL's Cetane Booster, which improves combustion efficiency to increase power in diesel engines.

There are plenty of first-hand testimonials on the Forum as to its validity to perform as advertised. FYI - AMSOIL's Cetane Boost will raise a diesel fuel's rating up to seven numbers, depending on the dosage. Other benefits include low temperature starting, fuel ignition quality, and improved reliability of the engine in general.

One 16-oz stainless steel can treats up to 200 gallons if you want a 3 1/2 point increase or service 100 gallons for a full 7 point boost. For more technical info about this excellent product, please feel free to send me an e-mail at sjporter2@juno.com .



Performance Features

* Improves ignition quality
* Improves low-temp starting
* Reduces cranking time
* Reduces emissions and smoke
* Provides smoother, quieter operation
* Increases efficiency
* Compatible with other diesel fuel additives

Product Code ACB - http://www.amsoil.com/products/acb.html
LMAO,
DB
 
Last edited:

b4black

Veteran Member
Joined
Dec 18, 2004
Location
IL
TDI
1998 Jetta blue
dieseldorf said:
How "pure" is the HiTEC product?
> 99%


Sometimes you can find the % in aftermarket additives by ssearching for the MSDS. 2EHN is hazardous enough to require it's concentration to be listed in the ingredients section. The may deguise the name, so look for CAS# 272-47-96-7. The rest of the additive is mostly kerosene (a.k.a. "petroleum distillates).
 
Last edited:

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
Thanks, B4.

The product from Amsoil is also ~99% pure.
 

b4black

Veteran Member
Joined
Dec 18, 2004
Location
IL
TDI
1998 Jetta blue
So what treatrate do they recommend? Something like 0.1%?

Cocktail additves are usually something like a quart in 100 gallons or 0.25%. Then you have to factor in the concentation.
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
They call it 1600:1 for a 3pt bump



You'd add 1.2 ozs for a 15 gallon fillup.
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
Interesting...I don't know the answer to that. I guess we could ask them.

I did review the MSDS yesterday and the ingredient and strength appear to be the same unless that sheet was not updated.

Thx. for the heads up.

BTW, are you running this as your only additive or in conjunction with something else? Any changes noted?
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
OK, per the website, it reads:

1300:1 for a 3pt bump
650:1 for a 7pt bump
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
to throw a bit more fuel on the fire ;)

SAE paper/Abstract:

A 1,000-hour test was conducted to determine the durability effects of 2-ethylhexyl nitrate (2-EHN) cetane improver on heavy-duty diesel engines. Two identical 1993 DDC Series 60 were run side-by-side on a severe duty cycle. Both were fueled with a commercial low sulfur fuel. The fuel in one engine was treated with 7500 ppm of 2-EHN cetane improver. At the end of the test, engine wear and deposit comparisons were made to determine the effect of high cetane improver treat rates on engine durability.


After 1,000 hours of operation, the engine running on fuel treated with 2-EHN cetane improver exhibited lower engine wear and deposits than the engine run without cetane improver. Analysis of oil samples drawn every 100 hours indicated no difference in wear metals or other physical properties when cetane improver was used. Fuel analyses demonstrated that 2-EHN did not degrade under the high operating temperatures of this modern heavy-duty diesel engine.

File Size: 68K

Product Status: In Stock

See other papers presented
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
Yeah, there are some minor benefits. I think they've got to be weighed against the cost.

If you look thru that Chevron piece I posted above, you'll see there exists some uncertainty about using this cetane booster on ULSD... some batches of fuel are labeled "slow response" and other are considered "fast responese". They suggest that the cetane booster may have no effect on some batches of fuel.

Here's another interesting piece (from SAE) concerning a Toyota Avensis on the rollers at the EPA lab in Ann Arbor. They've extensively documented the impact of emissions and the use of this particular cetane booster. The paper is from 2002.


http://www.4cleanair.org/Oldmembers/members/committee/mobile/TestingToyota.pdf
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
Toyota, BMW agree: More is better!

(Fall 2003)

Newport, R.I. -- Both Toyota and BMW see possibilities for introduction of diesel cars into the North American market but only if ultra-low sulfur diesel (ULSD) also improves with consistently higher cetane and lower aromatics.

Toyota's novel "DPNR" system simultaneously slashes nitrogen oxides (NOx) and particulate matter (PM) with a novel "low-temperature combustion" scheme employing "massive" exhaust gas recirculation (EGR) and a combined PM/NOx trap.

But Toyota bluntly told the Diesel Engine Emissions Reduction (DEER) conference here (sponsored by U.S. Department of Energy) that U.S. diesel fuel is generally poor and highly variable on cetane/aromatics, making it harder to design an engine/emissions control scheme for North America.

Rather than the very low 40-cetane minimums/35% aromatics maximums allowed under U.S. EPA 2006 diesel rules, Toyota instead urges an over-50-cetane number minimum and aromatics levels more like those of California Air Resources Board (CARB) diesel (averaging around 21%, although the default limit is 10%).

"It is essential that diesel fuel cetane and aromatics must improve," Toyota powertrain general manager Tetsu Watanabe said here. "Fuel quality is a big problem--low average cetane number (44) and aromatics are high--35% average and 54% maximum in the U.S."

Ironically, Toyota showed that its "DPNR" test car fleet in Europe is meeting European emissions and performance goals even in countries with 300-ppm sulfur fuels.

However, Europe lacks the ultra-strict NOx/PM limits of U.S. EPA for Tier 2/Bin 5 or the equivalent California LEV-2 limits--and high-frequency desulfation threatens catalyst durability.

For emissions limits testing at U.S. EPA's laboratory in Ann Arbor, Mich., Toyota's DPNR car (with an European engine control calibration) used a 6-ppm sulfur fuel of 50.4 cetane and 26% aromatics, he said. While this car did very well on most EPA test modes, it fell short on "US06" mode and still hasn't proven EPA's 120,000/150,000 miles durability (see Diesel Fuel News 6/24/02, p6).

In contrast, Europe and Japan will have much better cetane/aromatics limits as well as ultra-low sulfur diesel (ULSD) by 2005, enabling "DPNR" cars in Europe and "DPNR" light trucks in Japan.

For the DPNR light truck, Toyota will employ an under-floor-mounted catalyst. In tests of over 200,000 kilometers, Toyota has found that this vehicle's NOx storage capacity works better with a 7ppm sulfur ULSD rather than a 40-ppm sulfur fuel.

BMW's Conquering Diesels

Meantime, BMW's sensational diesel sports cars (including test-drive cars supplied to DEER conference here) are tearing up the European market, as diesels now account for 68% of BMW-Europe sales compared to 35% world-wide, BMW official Fritz Steinparzer showed here.

"Particularly in the U.S. and some parts of Asia, the combination of a car in this [high-performance] segment with a diesel engine was up until now almost unthinkable--I feel sure that many people in the USA are not even aware that BMW produces diesel-powered cars," Steinparzer explained.
Now, thanks to huge strides in engine performance, BMW-Europe buyers actually prefer diesels over petrol engines, but its diesels aren't available in the U.S.

Upgrades in maximum cylinder pressure, common rail pressure, multi-injection (four events), boost pressure, turbine and compressor efficiency, fuel efficiency and ultra-low PM emissions (thanks to a new diesel particulate filter) mean BMW can achieve outstanding performance, low C[O.sub.2], and ultra-low criteria emissions--except for NOx.

Although BMW's latest engine/DPF technology can meet Euro standards, "the future NOx limits [in the U.S.] are very challenging and the development of new technologies is necessary," he said.

Aiding emissions compliance would be "better fuel quality similar to" European ULSD standards (much higher in cetane than U.S. average) and "slight legislation adaptations to take account of the specific diesel advantages" for long-term emission stability and C[O.sub.2]. However, U.S. EPA isn't inclined to relax NOx/PM limits in exchange for lower C[O.sub.2] (see Diesel Fuel News 3/18/02, p10).
 

b4black

Veteran Member
Joined
Dec 18, 2004
Location
IL
TDI
1998 Jetta blue
dieseldorf said:
OK, per the website, it reads:

1300:1 for a 3pt bump
650:1 for a 7pt bump
1300:1 is 0.08%
650:1 is 0.15%

How about other additives besides AMSOIL?
 

dieseldorf

Top Post Dawg
Joined
Oct 11, 2000
Location
MA
TDI
ex- 1996 wagon, ex-2000 Jetta
I suspect many of the mainstream additives utilize 2 EHN as a basic cetane booster. It's the most common additive.

I don't really know of any other that are rate at ~99% purity. I suspect the product is good. One of their other products may be a bit more broad-based in terms of water removal and injector cleaning power.
 

Ton

Veteran Member
Joined
Jan 20, 2009
Location
Free Union,VA
TDI
early 2001 jetta
The sun is shining.

Where is the thread for bio-based fuel additive? I found some in an upstate New York truck stop. I forget the brand name.
 
Top