Apathy killed it
ABSTRACT
Details the conception of totally unique method of construction of a Structural Element Battery and its manufacturing process. Improves upon current state of the art laminate sheet web-press formed Lithium-ion polymer batteries with ultrasonic joining being employed in addition to enhanced interlayer adhesion by design: Takes advantage of the natural ‘fuzziness’ of graphite cloths for hook-and-loop assisted interlayer joining. Carbon nanorod functionalized graphite anode for improved lifetime cycling. Report includes case studies and examples of potential applications of the invention.
RELEVANT KEYWORDS (Optional)
Lithium ion polymer battery, multifunctional, carbon nanorod functionalized surfaces.
DETAILED DESCRIPTION OF THE INVENTION
Project:
Description and claims of the uniqueness of the invention of a Structural Element Battery and some selected applications which will highlight the usefulness, efficacy, and completely novel, unconventional solutions to the existing set of problems and practical difficulties in designing batteries for mobile and highly mobile applications: especially those applications requiring motive power from their battery. It is intended to lay out clear and compelling evidence, argumentation, and case studies to develop in the reader the fundamental understanding, the unconventional synthesis of ideas, conceptions, and processes which lead to the elegantly simple solution to the existing difficulties of battery design—The Structural Element Battery (SEB.)
The SEB battery solution is without equal in its approach or conception.
Goals: Ever since the OPEC oil crisis of the early 1970’s, and again now, it has been highly desired to have personal vehicle powered by an electric battery. Historically, electrically powered cars were among the first to be produced at the turn of the 19th/20th centuries. Yet for all practical intents since then, the battery has been limited to small portable consumer electronics and low-power devices; it has been largely shunned as a power source for vehicles because of grossly insufficient energy density (how much range) and power density (how much acceleration.) Recent advances in Lithium-ion polymer electrolyte batteries have improved the energy and power densities to roughly 500 wh/Kg and 520 w/Kg, which is good. However, it is not good enough.
Electric Vehicle as Case Example:
It is generally accepted that no electric vehicle will reach mass-market penetration into the family garage until it can travel ca. 225-300 miles non-stop and accelerate to freeway speed in a reasonable time, ca. 14 seconds. With the current approach to design, a battery manufacturer would produce a battery to meet these energy and power requirements for a vehicles wherein approximately equal parts of added weight (mass) are required to accelerate and hold constant speed for an average family subcompact sedan. Now, the vehicle has gained much additional mass: 35% or more gain over its original weight. Therefore, a vicious circle is entrained wherein meeting one set of requirements (acceleration and cruising needs) adds significant new mass to the vehicle, increasing the horsepower needed to meet those requirements! This added mass in turn dictates that the other vehicle components: suspension, motor management and mounting, frame stiffness be upgraded to handle the additional weight, of course adding more weight to the ever-increasing conundrum. At some point, the engineer cannot satisfactorily meet either objective and must instead compromise one way or the other toward range that is more acceptable (barely) or acceptable acceleration results (even more difficult.)
What is the effective solution which removes the frustrations?
Background:
In the late summer of 1999, the author became aware of pioneering work in this field by researchers at Sandia National Labs. They had taken a commodity-grade textile fabric (polyacrylanitrile—PAN cloth) converted it to pure graphite form and then intercalated it electrochemically with lithium ions—thus forming the negative (anodic) electrode of a lithium-ion battery.
A different kind of solution gripped the author: Make the battery a structural, load-bearing element! If fully one-third of the three things required to make a battery: anode, cathode, electrolyte, can be made out of carbon-fiber—one of the lightest and strongest materials, then why can’t the other materials be carefully chosen to be effective chemically, but stiff and mechanically rigid as well?
There is no fundamental limitation or constraint which says a battery must fit inside the device it is powering, only mere convention. Therefore, why not make the net shape of the object—the package, or the outline form of the object, as it were,—its own power source?
In this way, the conundrum is defeated at its very root. There is little or no addition of weight/ mass because the new SEB battery is replacing the existing mass of two things: the OLD structure and the OLD battery with its heavy casing. In most cases it is expected that SEB design will accomplish the same structural rigidity and physical integrity while meeting both acceleration/ steady state power requirements using LESS mass than previous conventional designs.
The solution to the conundrum is simple: see the battery not in package form; see the package as battery-form. This reorganizing of the problem from a chemically limited technology to a packaging limited framework opens up a previously inaccesable, virtuous circle.
Now that the mass of the original body/frame of the case vehicle has been reduced, so too can the masses of the motors, brakes, generators, suspension. In addition, the power requirements satisfying the original demands can be downsized to meet the newly reduced mass.
Case Example of the Virtuous Circle:
If the original steel body and frame of a typical family sedan, as depicted in figure 1, were 2000 lb… traditional design incorporates the unibody or semi-unibody design. Unibody or unit-body design incorporates one or more frame or sub-frame assemblies made of steel, wherein the main body, known as the body-in-white, bears the torsional, lateral, longitudinal stresses and provides the attachment or ‘hard points’ for driveline, suspension, glass, trim pieces, etcetera. A typical mid to full sized, 4-door family sedan weighs 3200-3800 lbs, dry (no fuel, oil, fluids.) Of that, the unibody of steel comprises 1900-2000 lbs, depending on dimensions and sheet steel thickness.
If instead, the unibody were functionalized as a Structural Element Battery…
At 300 volts (for efficiency), each cell at 3.9 volts nominal requires 77 serially stacked layers (cells) of 0.65mm each, equaling ca. 5 cm thickness. A body design utilizing the Structural Element Battery approach can also utilize unit body, or modularized unit-body with detached/separate crash-safety crush zones. Since there is no liquid electrolyte to spill, there are no chemical or explosion hazards.
Moreover, in failure tests previously done, a lithium-ion stacked cell was penetrated with a nail fired from a nail gun while in discharge. In that test, cell voltage dropped to slightly more than half and then slowly recovered to ~70% of its prior voltage, discharging all the while. It did not explode, rupture, or fail. Its ability to withstand penetration trauma without complete failure and no compromise in safety while retaining some reserve power/energy discharge capacity makes lithium-ion polymer technology extremely attractive and safe.
To summarize the advantages of SEB design philosophy:
Inert mass replaced with power functional mass
Fewer hard mount points required (since not required to carry internal battery), and hence, fewer body through-holes. Body rigidity increased. Main body section integrity during crashes increased.
Less need for (inert) trim panels to hide ugly body and ugly body holes since SEB battery assumes net shape of exterior design, even for surfaces having complex or compound curvature.
Fewer inert body panels and trim pieces means a greater % of the vehicle mass is power-functional and a lower % is wasted, dead weight mass.
Because of these two significant sources of mass-reduction (higher functional mass% and lower waste mass %) lower the acceleration and cruising power requirements by way of the virtuous circle.
Lowering the power requirements means smaller, lighter motors, which in turn allows smaller, lighter suspension, electrical cabling, and braking components.
The increased surface area of the battery—achieved by ‘pushing out’ the Structural Element Battery to the net final envelope of the body—means that it can produce more current and yet stays cool. Combined with the reduced mass and power requirements, these two factors work synergistically to reduce the requirements of onboard rechargers.
The virtuous circle goes around again for another set of weight/mass reductions—in exact opposition to the original conundrum, reaching a final design which makes no compromises in range or acceleration—and yet is safer than conventional battery design.
Case example: Comparison of SEB hybrid to Toyota Prius Hybrid:
The Toyota Prius is a hybrid-designed car employing advanced motor controls and two power plants: a 44 hp electric motor powered by a nickel-metal hydride battery pack and a 1.5-liter 4 cylinder (4-stroke) internal combustion engine (ICE.) The Prius body is made of aluminum and is 40% lighter than a conventional steel body. A table of some selected weights and relative mass % gives a clear picture of the Prius:
Table 1: Selected component weights and their
weight relative to total.
Part
Weight (lbs)
% of Total Weight
Body
1847
66.8
Battery
110
3.98
Engine
194.7
7.04
Total
2766
77.82
Fully two-thirds of this vehicle’s mass is inert, dead weight!
Remember, from the battery mass calculations above (needs correction), that a car with similar weight needed 694 lb of lithium-ion polymer battery mass to meet the original range and acceleration requirements, unaided by onboard ICE generators. Thus, if we replaced the Prius’ aluminum body with a 700 lb. Structural Element Battery, then fully 1147 lbs are lost for a 41.5% mass reduction! Our SEB designed vehicle also loses the 110 lb. NiMH battery pack, for a net mass reduction of 45.4%
Now, the vehicle only weighs 1509 lbs and no longer needs as much power to meet the acceleration/range criteria, and entry into the virtuous circle nets additional positives. Moreover, the cost of ‘upgrading’ to the SEB design body is largely offset by the loss of the aluminum body (which is very difficult and expensive to form and weld.) Combined with the loss of the NiMH battery—an explosion and caustic crash hazard as well as an environmental pollutant, entry into the virtuous circle leads to unexpected benefits beyond mass reduction.
In fact, the case for larger SUV-type vehicles is even more virtuous because of the increased surface area= increased current and power delivery capacity. In addition, battery life increases because of lower heat (lower current/area density and more surface cooling) since SUV’s have a lot of surface area relative to their masses. Consumers prefer large, comfortable SUV’s. They are perceived as being safer also. Due to the outlined factors, and because manufacturers profits are greater from their sales, they are an ideal target market for SEB design.
Description of the Author’s Invention, the SEB Battery and Design Concept:
A method of construction for a lithium-ion polymer secondary (rechargeable) battery, which can be made rigid and strong to bear physical loads.
An outline of the general approach following a four-part scheme: The bulk production of ‘raw’ battery material, the processing of such raw material into rigid and strong final net shapes, the ‘finishing of the battery into usable arrays, and the operational control of the battery.
Production method for raw or uncured battery material.
A chemical/ heat treatment method for converting PAN cloth into graphite using Sandia’s methods.
A chemical treatment to prevent internal shorting wherein the inward-facing side of the carbon cloth anode is treated in a rarified environment and exposed to an acetylene ionizing flame. A process wherein the acetylene flame front converts the naturally occurring ‘fuzz’ or surface fibers on the order of tens of microns in length having an orientation normal to the graphite cloth plane to carbon nano-rods, having more compact dimensions. A method wherein the carbon nano-rod functionalized surface, placed toward the electrolyte layer, enhances the electron migration to and fro between anode lithium ions, expanding the battery lifetime.
A chemical and mechanical joining process wherein the carbon fiber graphite anode cloth is joined to an UHMWPE gel electrolyte layer utilizing ultrasonic-assisted mechanical joining.
A chemical joining process wherein a lithiated composite Lix:CoO2 + Liy:MnO2 cathode material is sprayed on the UHMWPE gel electrolyte on the side opposite the carbon anode.
A mechanical joining process wherein a polyphthalocyanine-copolymerized Kevlar® fabric is joined to the cathode side of the UHMWPE layer utilizing ultrasonic-assisted mechanical joining.
A chemical spraying process wherein an (commercially available) electrically activated, electrically conducting, polyphthalocyanine-based adhesive is sprayed on the backside of the carbon anode for interlayer joining.
A method of fabrication wherein uncured, ‘raw’ battery films produced in the previous step, having a
cell thickness< 1 millimeter, are successively joined together, a few layers at a time, in laminar
sandwiches for additive voltages and cured into strong and rigid conformal net shapes.
A process employing negative mold vacuum-bagging vacuum forming techniques and airbags, wherein a collapsible, ultrasonic transducer array is inside the airbag for ultrasonically assisted chemical/mechanical joining.
An electrochemical-mechanical-ultrasonically assisted, vacuum forming method for curing the battery layers to rigid and strong, conformal net shapes wherein the outer skin of the airbag, as well as the inside surface of the negative mold, having a conducting surface, are electrically charged. A process wherein the electrical charge serves to activate and cure the polyphthalocyanine based adhesives. A process wherein the battery is given first charge. A process wherein the electrical charge serves to initiate moderate cross-linking and polymerization of the UHMWPE, converting its gel form to a semi-rigid and stiff mechanical form, while not interfering with its electrolytic abilities.
An ultrasonically-assisted process wherein the ultrasonic array emits ultrasonic waves from the center of the negative mold outward, in a repeating pattern, to ensure no air bubbles are trapped between layers. A process wherein the ultrasonic waves enhance the physical and chemical joining of the layers.
A hook-and-loop type joining process, wherein the natural ‘fuzziness’ of carbon fiber and Kevlar® fibers assist the chemical joining of polyphthalocyanine adhesive by ensuring the interlayer mechanical shear strength integrity of multiply-stacked battery cell layers.
A method for ‘finishing’ a serially stacked battery.
wherein a software-driven, intelligent battery charge and discharge current controller is integrated into the surface of the battery.
A method of finishing the battery wherein exposed edges are hermetically sealed with hydrophobic, uv-resistant polymer or joined edge-to-edge in hydrophobic polymer.
A method of finishing the battery wherein battery to electric-bus connections are established. A method of connection wherein a copper bus-header is joined to the surfaces of the battery to conduct and direct in-plane battery charge to the positive and negative terminals of an electrical delivery bus.
A method for preparing hard-mount points for physical connection of motors, pumps, generators, and other ‘hard’ devices needing physical support. A method of making planned (prior to step 2) or unplanned ‘cut-outs’ and hermetically sealing their edges. A method for connecting ‘hard’ devices using UHMWPE bushings or long-life synthetic rubber grommets through said cutouts.
A method for coating both interior and exterior surfaces in uv-resistant polymer or colored paints.
A process of battery charging and conditioning wherein battery life and safety are maximized.
A software-based method wherein no single battery module, except a designated ‘fail-first’ module in a multi-module array, such as in a car body having more than one sub-assembly, shall never be fully discharged nor fully charged—preserving its life. A software based method wherein planned eventual failure is employed: one battery module, having been selected by computer as the weakest battery, is cycled more intensively and to a greater charge/discharge margin, such that its lifetime will terminate first, preventing the owner from having to replace more than one module at once at great expense. A method for ranking battery modules based on replacement cost and replacement difficulty, such that the fail-first module is never the most expensive/difficult to replace module but rather one of the cheaper/easier to replace modules. A method for notifying owner of the need to replace designated ‘fail-first’ module prior to actual failure, giving predicted date and time of end-of-life. A method wherein ‘fail-first’ battery is replaced before actual failure so that that module may be reused in a less demanding application (i.e. electric utility load leveling) to reduce the needs for waste processing or recycling. A method for designating the weakest battery in the array as the ‘fail-first’ battery after replacement. A software-based method which monitors and controls all aspects of the charge/discharge profile for maximizing lifetimes. A software-based user interface which determines user preferences: commute range, weekend use, price of local utility electricity, price of fuel for onboard generator—in order to determine optimal and most cost-effective charging of battery arrays.
It may be instructive to describe the proposed battery chemistry (which can be easily modified or improved under further development.) In attached figure 2, layer A. serves to join one layer to the next adhesively, while conducting electrons for serial voltage stacking. Layer B is carbon anode (graphite fabric sheet) surface processed on the side facing the electrolyte, such that the natural ‘fuzz’ is converted to carbon nano-rods, serving to aid in electron transport, extending battery life. Graphite cloth’s natural ‘fuzz’ on the other side (facing layer A) serves to aid in hook-and-loop assisted fastening, improving resistance to mechanical shear stresses. Layer C is an Ultra High Molecular Weight Poly Ethylene(UHMWPE) film in ‘gel’ form (no cross-linking and chemically a gel state.) Once cured, it will provide rigidity and lateral and longitudinal strength, as well as electrolytic functionality. Layer C is a spray deposited cathode sol-gel solution of CoO2 and MnO2 on the UHMWPE gel electrolyte, preventing flaking or cracking by integrating the cathode into rigid electrolyte. Layer E is a polyphthalocyanine/polyaramid (like Kevlar®) graft copolymer fabric which conducts electricity and provides good adhesion surface of high surface roughness to next laminate layer. Because carbon and aramid fabrics are both naturally quite ‘fuzzy’, wherein the fuzz is on the order of tens to hundreds of microns in length, these two surfaces add hook-and-loop mechanical shear stress and strain resistance to the interlayer adhesive of layer A.
A pictorial cartoon type description of the roll forming process to make raw battery material is shown in figure 3. It follows existing roll-forming processes, excepting its unique application of ultrasonically assisted physio-chemical joining. The resultant product of this stage of manufacture is a sonico-physically bonded battery cell which will charge to 3.9 volts later. Being less than 1 mm thick and having an electrolyte in gel form, it is still ‘drapable’ in fabrication industry terms. That is, it can conform to a mold shape without kinking or breaking.
Sold as bulk sheets or rolls, the Lithium-ion cells can then be shipped (sealed) to a final stage manufacturer to make net conformal shapes of any mobile product: cell phones, laptop computers, electric vehicle body, unmanned aerial vehicle, model airplanes, RC cars, wearable vest panels in bullet-resistant soldier’s jackets, etcetera.
At this stage of production, the battery cells will be unpacked, cut to correct shape/size and draped one atop the other (serially) a few layers at once into a negative mold using air bag and vacuum bag forming technology. The cell will be pressed by positive airbag pressure on the inside of the mold, and held to the mold with negative pressure by vacuum bagging. In this way, the cell will be under lateral and longitudinal tension in both x and y directions (pre-stressing the net shape for greater stiffness.)
A potential voltage or a gamma ray source will initiate moderate cross-linking polymerization of the UHMWPE electrolyte layer, but not enough to interfere with its electrolytic abilities. The applied voltage will serve to active the adhesive properties of polyphthalocyanine or other electrically activated and conducting resins which are commercially available now.
In this way more layers will be added sequentially until a final desired battery voltage capacity or thickness has been reached. A sonic transducer array inside the airbag aids in sonico-physio-chemical bonding.
Finally, as in the electric car example before, the net shapes of the body-in-white, doors, hoods, trunks, seats can be joined to an common electric distribution bus by copper or silver thin films (covered in separate patent.) Bus connects may be integrated into the surfaces of each battery in a multi-module array during the shaping/curing phase.
In addition, it may be possible to integrate the new flexible polymer photovoltaic solar cells now commercially available into the top surface of any device which may get significant sunlight to aid in trickle charging the battery.
Benefits unique to the design:
Extreme puncture resistance. UHMWPE and aramid layers both are currently marketed as ‘bullet proof’ jacket materials. Bullet or projectile resistant (degree depends on total thickness.)
Puncture fault tolerance, providing limp-home capability.
‘Fail-first’ concept and software-driven battery charge/conditioning minimizes catastrophic whole-system failure and minimizes cost by maximizing replacement interval. ‘Fail-first’ can isolate shorting, damaged, or punctured cells.
Software-driven charging algorithms maximize overall battery lifetime, reducing replacement cost and interval. Software-driven algorithms can be adaptive—they can change charging currents and priorities based on readings of battery assemblies, especially in the case of puncture or damage.
UHMWPE electrolyte prevents thermal runaway.
Exceptionally strong, light.
Replaces existing structural and battery mass, making its effective energy/power density many-fold more than that of any existing battery technology—recall that implementation of SEB design can reduce total vehicle weight by ~45% over best competing technology.
SEB design replaces more weight than it adds.
POSSIBLE APPLICATIONS (Optional)
Electric and hybrid electric vehicles, including military transport. Laptop computers, portable electronic devices: pda’s, Blackberry’s… Military light portable power (bullet resistant.) Military bullet-resistant wearable, powered vests or vest panels. Military unmanned aerial vehicles. Remote-controlled airplane and remote-control hobbyists. Any application where portability and weight/mass are dominating factors.
PRIOR ART (Optional)
UHMWPE-based gel polymer electrolyte developed by DOE funded CRADA at Amtek International of Lebanon, Oregon. PAN cloth treatment to yield graphite cloth anode developed at Sandia. Portions of web-press joining of lithium-ion polymer battery cells (not ultrasound) developed at PNNL. Entek International ©, parent company of Amtek (research division) has extensive experience in UHMWPE electrolyte and solution-sprayed cathode material—may be a good partner?
PRODUCT DIFFERENTIATION (Optional)
Tackles the weight conundrum at its root and solves it, yielding entry into the virtuous circle. Does not suffer the need for heavy protective exterior packaging. UHMWPE electrolyte ensures thermal overload protection, melting at about 300 oC, it prevents fire or explosion. Battery charger/conditioner method designates a ‘fail-first’ module, keeping replacement costs minimal and at intervals, rather than having to replace all at once.
STATUS OF THE INVENTION (Optional)
ADDITIONAL CONSIDERATIONS (Optional)
Hand-drawings (not shown here.)