In some 3-valve heads, there are two intakes, each of which are smaller than the single exhaust. That's pretty rare.
well, id say to that extent that the volume still is greater for the 2 intakes vs the exhaust. I know on the gy6, there is a 4 valve head, and even with porting, its actually less volume of air moved vs just the 2 valves.
Even 2 stroke engines, port or valved head, have larger intakes, but when port 2 stroke, i always see 2 or 3 smaller intakes as there is not much room for a single large intake, also fuel mixing and exhaust band tuning and so on.
Frank06 is our resident expert on heads, so im sure he is the guy to talk to around here on this subject.
heck even rotary engines and STEAM engines have larger intake ports, especially in steam