From the bottom, up on a lift or jackstands for most of us.
On some vehicles it may help to pull some hoses and tie them out of the way. Just an inch or two can be invaluable.
By the way, while it seems that in 5% of the reports, replacing the RCV does not fix the issue, or it fails again soon, my experience, with about a dozen of them, is that it does fix it for an extended time - years.
Please remember that if your AC compressor oil is not clear amber color, with no metal flakes in it, the compressor is bad, and the RCV will not help long. All it takes is one tiny metal flake in the valve to cause it to stick. Dark brown or black oil or metal flakes means you must flush the system and put in a new compressor.
While the product may be snake oil, or worthless, I usually
add a can of 1 oz. ICE32 additive, 1 oz. PAG oil, and 1 oz Ri34a immediately after the valve install, as the first part of the charge, done with the engine off. I hold the can upside down to get the liquid out (Which I would not do on a running compressor - 5 cc of liquid on a piston will hydrolock it and ruin the compressor) then with the engine still off put in 12 ounces of R134a, as a gas, to push the oil in, and to spread it out in solution through the system.
The can in the link has the oil, ICE32 and one ounce of R134a in it, though this is not clear from the product description anywhere on the web that I can find. It does say so on the back of the can.
A bucket of hot tap water (120 F or so) is very useful to keep the refrigerant boiling out of the can rapidly. I tie a wire on the bucket bail to hold the cans upright, so I get gas, not liquid.
Read the manual or the sticker under the car for the total amount of R134a to add. For most of the MK Vs, it is about 18 ounces or so - a can and a half.
I worked on 3 of these for family and friends in the last week. In each case the air temperature went from 60F or so before the repair to 38-40 F, when running the fan in fast, full cold, recirc mode, at 2300 rpm engine speed. This was in direct sunlight in 90 F weather.